IndiumV3, Main, Repository, bibRecord, 005148

Initial molecular orientation of phthalocyanines on oxide substrates

Identifieur interne : 005148 ( Main/Repository ); précédent : 005147; suivant : 005149

Initial molecular orientation of phthalocyanines on oxide substrates

Auteurs : RBID : Pascal:10-0049415

Descripteurs français

Pascal (Inist)
- Orientation moléculaire, Irradiation ion, EXAFS, Adsorption, Couche adsorbée, Orientation préférentielle, Complexe de cuivre, Phtalocyanine métallique, Oxyde, Couche ultramince, Couche mince.
Wicri :
- concept : Oxyde.

English descriptors

KwdEn :
- Adsorbed layers, Adsorption, Copper complexes, EXAFS, Ion irradiation, Metallophthalocyanine, Molecular orientation, Oxides, Preferred orientation, Thin films, Ultrathin films.

Abstract

The molecular orientation of ultra-thin films of copper phthalocyanine and perfluoro-copper phthalocyanine (F₁₆PcCu) on various oxide substrates is examined with polarisation dependent NEXAFS spectroscopy. The focus is on the adsorption geometry of the first adsorbed layers, which can strongly vary from the observed orientation in thin-films above the few nanometre regime. Native silicon dioxide, indium tin oxide and titanium dioxide are chosen for their relevance to technical applications. On chemically and thermally cleaned oxide surfaces a predominantly standing initial orientation is preferred, while on ion bombarded activated surfaces the molecules prefer a lying orientation.

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Pascal:10-0049415

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Initial molecular orientation of phthalocyanines on oxide substrates</title>
<author><name sortKey="Biswas, Lndro" uniqKey="Biswas L">Lndro Biswas</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Institut für Physikalische und Theoretische Chemie, Universität Tübingen, Auf der Morgenstelle 8</s1>
<s2>72076 Tübingen</s2>
<s3>DEU</s3>
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<country>Allemagne</country>
<placeName><region type="land" nuts="1">Bade-Wurtemberg</region>
<region type="district" nuts="2">District de Tübingen</region>
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</author>
<author><name sortKey="Peisert, Heiko" uniqKey="Peisert H">Heiko Peisert</name>
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<settlement type="city">Tübingen</settlement>
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<author><name sortKey="Casu, Maria Benedetta" uniqKey="Casu M">Maria Benedetta Casu</name>
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<author><name sortKey="Schuster, Britt Elfriede" uniqKey="Schuster B">Britt-Elfriede Schuster</name>
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<author><name sortKey="Nagel, Peter" uniqKey="Nagel P">Peter Nagel</name>
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<author><name sortKey="Merz, Michael" uniqKey="Merz M">Michael Merz</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Forschungszentrum Karlsruhe, Institut fiir Festkörperphysik</s1>
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<author><name sortKey="Chasse, Thomas" uniqKey="Chasse T">Thomas Chasse</name>
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<s2>72076 Tübingen</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
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<region type="district" nuts="2">District de Tübingen</region>
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<term>Adsorption</term>
<term>Copper complexes</term>
<term>EXAFS</term>
<term>Ion irradiation</term>
<term>Metallophthalocyanine</term>
<term>Molecular orientation</term>
<term>Oxides</term>
<term>Preferred orientation</term>
<term>Thin films</term>
<term>Ultrathin films</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Orientation moléculaire</term>
<term>Irradiation ion</term>
<term>EXAFS</term>
<term>Adsorption</term>
<term>Couche adsorbée</term>
<term>Orientation préférentielle</term>
<term>Complexe de cuivre</term>
<term>Phtalocyanine métallique</term>
<term>Oxyde</term>
<term>Couche ultramince</term>
<term>Couche mince</term>
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<front><div type="abstract" xml:lang="en">The molecular orientation of ultra-thin films of copper phthalocyanine and perfluoro-copper phthalocyanine (F<sub>16</sub>
PcCu) on various oxide substrates is examined with polarisation dependent NEXAFS spectroscopy. The focus is on the adsorption geometry of the first adsorbed layers, which can strongly vary from the observed orientation in thin-films above the few nanometre regime. Native silicon dioxide, indium tin oxide and titanium dioxide are chosen for their relevance to technical applications. On chemically and thermally cleaned oxide surfaces a predominantly standing initial orientation is preferred, while on ion bombarded activated surfaces the molecules prefer a lying orientation.</div>
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<fA11 i1="01" i2="1"><s1>BISWAS (Lndro)</s1>
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<fA11 i1="02" i2="1"><s1>PEISERT (Heiko)</s1>
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<fA11 i1="03" i2="1"><s1>CASU (Maria Benedetta)</s1>
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<fA11 i1="04" i2="1"><s1>SCHUSTER (Britt-Elfriede)</s1>
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<fA11 i1="05" i2="1"><s1>NAGEL (Peter)</s1>
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<fA11 i1="06" i2="1"><s1>MERZ (Michael)</s1>
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<fA11 i1="07" i2="1"><s1>SCHUPPLER (Stefan)</s1>
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<fA11 i1="08" i2="1"><s1>CHASSE (Thomas)</s1>
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<fA14 i1="01"><s1>Institut für Physikalische und Theoretische Chemie, Universität Tübingen, Auf der Morgenstelle 8</s1>
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<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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<sZ>6 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The molecular orientation of ultra-thin films of copper phthalocyanine and perfluoro-copper phthalocyanine (F<sub>16</sub>
PcCu) on various oxide substrates is examined with polarisation dependent NEXAFS spectroscopy. The focus is on the adsorption geometry of the first adsorbed layers, which can strongly vary from the observed orientation in thin-films above the few nanometre regime. Native silicon dioxide, indium tin oxide and titanium dioxide are chosen for their relevance to technical applications. On chemically and thermally cleaned oxide surfaces a predominantly standing initial orientation is preferred, while on ion bombarded activated surfaces the molecules prefer a lying orientation.</s0>
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<s5>04</s5>
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<s5>05</s5>
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<s5>05</s5>
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<s2>NK</s2>
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<s1>SUB</s1>
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<fN21><s1>032</s1>
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Initial molecular orientation of phthalocyanines on oxide substrates

Initial molecular orientation of phthalocyanines on oxide substrates

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri